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Specifically, the episode "Passing Through Gethsemane" 
I couldn't find a full episode that wasn't behind a paywall, but this compilation of clips covers much of the main story. If you can find the whole episode, it's worth watching. It's quite powerful, though the sub-story has to do with a former serial-killer ("former" because in the B5 universe, murderers aren't put to death, but instead have their personality wiped and a new one rebuilt; only the personality is lost instead of the whole body, so that the new person may repay their debt to society.)
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